Kinetics of 4-Nitrophenol Reduction with Black Tea Extract Conjugated Silver Nanoparticle Catalyst

Rokiy Alfanaar; Yuyun Yuniati; Devi Natalia; Rasidah Rasidah; Lilis Rosmainar; Pandu Gizta Rapi Paksi; Mulani Jeni Lestari Tampubolon

doi:10.26555/chemica.v10i1.25404

Kinetics of 4-Nitrophenol Reduction with Black Tea Extract Conjugated Silver Nanoparticle Catalyst

Rokiy Alfanaar, Yuyun Yuniati, Devi Natalia, Rasidah Rasidah, Lilis Rosmainar, Pandu Gizta Rapi Paksi, Mulani Jeni Lestari Tampubolon

Abstract

The 4-nitrophenol reduction process is one of the slow methods. One way to increase the rate of 4-nitrophenol reduction reactions is to use a catalyst. In this study, the catalyst used was silver nanoparticles conjugated by black tea extract. The stages that have been carried out in research are the synthesis of conjugated silver nanoparticles of black tea extract, the determination of the kinetic profile of 4-nitrophenol reduction, and the study of the influence of inorganic anions on the reduction of 4-nitrophenol with the presence of silver nanoparticle catalysts. The presence of conjugated silver nanoparticles of black tea extract has been shown to increase the kinetics of the degradation reaction of 4-nitrophenol compounds to 85 times compared to without nanoparticles, by changing the value of the reaction rate constant from 0.00006 to 0.0051. The presence of inorganic anions provides information on the decrease in the rate of reduction reactions of 4-nitrophenol.

Keywords

4-nitrophenol; silver nanoparticles; kinetics

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References

M. H. Khamidun, M. A. A. Aziz, W. L. Chen, U. F. M. Ali, K. M. Isa, and N. A. Ahmad, “Removal of 4-nitrophenol from aqueous solution by using recycled carbon black from waste tyres,” Int. J. Environ. Waste Manag., vol. 27, no. 4, p. 455, 2021, doi: 10.1504/ijewm.2021.10037400.

US Environmental Protection Agency, “4-Nitrophenol (Regulation),” 2016.

G. Varank, A. Demir, K. Yetilmezsoy, S. Top, E. Sekman, and M. S. Bilgili, “Removal of 4-nitrophenol from aqueous solution by natural low-cost adsorbents,” Indian J. Chem. Technol., vol. 19, no. 1, pp. 7–25, 2012.

A. A. Yahya et al., “Removal of 4-nitrophenol from aqueous solution by using polyphenylsulfone-based blend membranes: Characterization and performance,” Membranes (Basel)., vol. 11, no. 3, pp. 1–20, 2021, doi: 10.3390/membranes11030171.

J. Luan and A. Plaisier, “Study on treatment of wastewater containing nitrophenol compounds by liquid membrane process,” J. Memb. Sci., vol. 229, no. 1–2, pp. 235–239, 2004, doi: 10.1016/j.memsci.2003.08.019.

J. Strachan, C. Barnett, A. F. Masters, and T. Maschmeyer, “4-Nitrophenol Reduction: Probing the Putative Mechanism of the Model Reaction,” ACS Catal., vol. 10, no. 10, pp. 5516–5521, 2020, doi: 10.1021/acscatal.0c00725.

P. A. Bolla, S. Huggias, M. A. Serradell, J. F. Ruggera, and M. L. Casella, “Synthesis and catalytic application of silver nanoparticles supported on lactobacillus Kefiri S-Layer proteins,” Nanomaterials, vol. 10, no. 11, pp. 1–16, 2020, doi: 10.3390/nano10112322.

M. Yusuf, “Silver Nanoparticles: Synthesis and Applications,” in Handbook of Ecomaterials, Switzerland: Springer Nature, 2019, pp. 2343–2356.

R. Javed, M. Zia, S. Naz, S. O. Aisida, N. ul Ain, and Q. Ao, “Role of capping agents in the application of nanoparticles in biomedicine and environmental remediation: recent trends and future prospects,” J. Nanobiotechnology, vol. 18, no. 1, pp. 1–15, 2020, doi: 10.1186/s12951-020-00704-4.

E. Kalantari, M. A. Khalilzadeh, and D. Zareyee, “Effective Reduction of Cr(VI) and Organic Dyes Using Pd NPs/Fe3O4@nanocellulose as a Recoverable Catalyst in Aqueous Media,” J. Inorg. Organomet. Polym. Mater., vol. 31, no. 1, pp. 319–330, 2021, doi: 10.1007/s10904-020-01784-3.

K. E. Sapsford, K. M. Tyner, B. J. Dair, J. R. Deschamps, and I. L. Medintz, “Analyzing nanomaterial bioconjugates: A review of current and emerging purification and characterization techniques,” Anal. Chem., vol. 83, no. 12, pp. 4453–4488, 2011, doi: 10.1021/ac200853a.

K. Pluta, A. M. Tryba, D. Malina, and A. Sobczak-Kupiec, “Red tea leaves infusion as a reducing and stabilizing agent in silver nanoparticles synthesis,” Adv. Nat. Sci. Nanosci. Nanotechnol., vol. 8, no. 4, 2017, doi: 10.1088/2043-6254/aa92b1.

S. Rajawat and M. S. Qureshi, “Comparative Study on Bactericidal Effect of Silver Nanoparticles, Synthesized Using Green Technology, in Combination with Antibiotics on Salmonella Typhi,” J. Biomater. Nanobiotechnol., vol. 03, no. 04, pp. 480–485, 2012, doi: 10.4236/jbnb.2012.34049.

N. A. Oladoja and E. B. Helmreich, “Oxyanions in Aqua Systems—Friends or Foes?,” in Environmental Contamination Remediation and Management Progress and Prospects in the Management of Oxyanion Polluted Aqua Systems, N. A. Oladoja and E. I. Unuabonah, Eds. 2021, pp. 1–31.

C. Wen, A. Yin, and W. L. Dai, “Recent advances in silver-based heterogeneous catalysts for green chemistry processes,” Appl. Catal. B Environ., vol. 160–161, no. 1, pp. 730–741, 2014, doi: 10.1016/j.apcatb.2014.06.016.

D. Handayani, A. Mun’im, and A. S. Ranti, “Optimation of green tea waste axtraction using microwave assisted extraction to yield green tea extract,” Tradit. Med. J., vol. 19, no. 1, pp. 29–35, 2014.

S. Iravani, H. Korbekandi, S. V Mirmohammadi, and B. Zolfaghari, “Synthesis of silver nanoparticles: chemical, physicIravani, S., Korbekandi, H., Mirmohammadi, S. V, & Zolfaghari, B. (2014). Synthesis of silver nanoparticles: chemical, physical and biological methods. Research in Pharmaceutical Sciences, 9(6), 385–406. ,” Res. Pharm. Sci., vol. 9, no. 6, pp. 385–406, 2014.

X. Kong, Z. Sun, M. Chen, C. Chen, and Q. Chen, “Metal-free catalytic reduction of 4-nitrophenol to 4-aminophenol by N-doped graphene.,” Energy Environ. Sci., vol. 6, no. 11, pp. 3260–3266, 2013, doi: 10.1039/C3EE40918J.

S. K. Srivastava, R. Yamada, C. Ogino, and A. Kondo, “Biogenic synthesis and characterization of gold nanoparticles by Escherichia coli K12 and its heterogeneous catalysis in degradation of 4-nitrophenol,” Nanoscale Res. Lett., vol. 8, no. 1, pp. 1–9, 2013, doi: 10.1186/1556-276X-8-70.

DOI: http://dx.doi.org/10.26555/chemica.v10i1.25404