REAKSI PENATAAN ULANG FRIES PADA EUGENIL ASETAT

kusmiyati kusmiyati, Sabirin Matsjeh, Jumina Jumina

Abstract


Fries Rearrangement of eugenyl acetate in order to study allilic substituent
group influence has been done. Fries rearrangement of eugenyl acetate was done by
heating at 120°C for 3 hours under AlCl3, dichloromethane as the catalyst and solvent,
respectively. The structure of the compound was identified using Infra Red
spectrometry (IR) and GC-MS. The result of te research showed that rearrangement
fries of eugenyl acetate are not formed, but yielded lightly brown oil of dimmer.


Keywords


Fries Rearrangement; eugenyl acetate

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DOI: http://dx.doi.org/10.12928/pharmaciana.v1i1.510

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Pharmaciana
ISSN Print: 2088-4559 | ISSN Online: 2477-0256
Website: http://journal.uad.ac.id/index.php/PHARMACIANA
Office: Faculty of  Pharmacy, Universitas Ahmad Dahlan
Jl. Prof. Dr. Soepomo, S.H., Janturan, Warungboto, Umbulharjo, Yogyakarta, Indonesia
Kode pos 55164
Email: pharmaciana@pharm.uad.ac.id