I²-MnO2 ACTIVATION OF PEROXYMONOSULFATE FOR CATALYTIC PHENOL DEGRADATION IN AQUEOUS SOLUTIONS

Edy Saputra, Syaifullah Muhammad, Hongqi Sun, Ha-Ming Ang, Moses O. Tade, Shaobin Wang

Abstract


I²-MnO2 was prepared and used to activate peroxymonosulphate for degradation of aqueous phenol. The sample was characterized by N2 adsorption, X-ray diffraction (XRD), scanning electron microscopy (SEM). The catalyst is highly effective in heterogeneous activation of PMS to produce sulfate radicals for phenol degradation compared with homogeneous oxidatiom. I²-MnO2 could completely remove phenol in 30 min at the conditions of 25 ppm phenol, 0.4 g/L catalyst, 2 g/L PMS, and 25 oC. A pseudo first order model would fit to phenol degradation kinetics and activation energy was obtained as 38.2 kJ/mol.


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DOI: http://dx.doi.org/10.26555/chemica.v1i1.502

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CHEMICA: Jurnal Teknik Kimia
ISSN: 2355-875X (print) 2355-8776 (online)
Organized by Department of Chemical Engineering - Universitas Ahmad Dahlan
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Email 1: chemica@che.uad.ac.id
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