Utilization of Fly Ash and Rice Husk as Chromium Metal Adsorbent in Batik Waste

Authors

  • Herawati Oktavianty INSTIPER Yogyakarta
  • Sunardi Sunardi INSTIPER Yogyakarta
  • Khairul Amri INSTIPER Yogyakarta

DOI:

https://doi.org/10.26555/chemica.v9i3.25105

Keywords:

fly ash boiler, rice husk ash, adsorbent, batik waste, chrom metal

Abstract

This study aims to produce adsorbents from fly ash boilers for palm oil mills and rice husk ash as adsorbents for batik waste. The research design used was Complete Block Design with 2 factors, namely the ratio of rice husk ash mass to fly ash boiler with 3 levels, namely A1 (25%:75%), A2 (50%:50%), A3 (75%:25%), and the concentration factor of HCl with 3 levels, namely B1 (1M); B2 (2M), B3 (3M), which is done 2 times repetition. The experimental stages include boiler fly ash pretreatment, rice husk ash pretreatment, synthesis and activation of adsorbents and adsorption tests on batik wastewater. Furthermore, analysis of COD, TSS and chromium was carried out. The results showed that the A3B2 sample provided optimal adsorption capacity for the analysis of COD, TSS and Chrom metal with values of 57.62 mg/L, 1.43 mg/L and 3.24 ppm, respectively, where there was a decrease in COD of 74%, a decrease in TSS of 97.56% and a decrease in chrom metal ion of 80.43%. This is due to the use of more rice husk ash with the use of HCl solution as an activator can increase the silica active group on the adsorbent thereby increasing the surface area of the adsorbent, where the surface area of the A3B2 sample is 118.24 m2/g.

Author Biographies

Herawati Oktavianty, INSTIPER Yogyakarta

Department of Agricultural Products Technology

Sunardi Sunardi, INSTIPER Yogyakarta

Department of Agricultural Products Technology

Khairul Amri, INSTIPER Yogyakarta

Department of Agricultural Products Technology

References

Ayoola, A. A., Fayomi, O. S. I., & Usoro, I. F., (2018), “Data on PKO biodiesel production using CaO catalyst from Turkey bones”, Data in Brief, Vol 19, 789–797. https://doi.org/10.1016/j.dib.2018.05.103.

Suparma, B. L., Panggabean, T. W., & Mude, S. (2014), “Potensi Penggunaan Limbah Kelapa Sawit sebagai Agregat Pengisi pada Campuran Hot Rolled Sheet-Base”, Jurnal Transportasi, 87-96.

Utama, P. S., Yamsaensung, R., & Sangwichien, C., (2018), “Silica gel derived from palm oil mill fly ash”, Songklanakarin Journal of Science and Technology, Vol 40(1), 121–126. https://doi.org/10.14456/sjst-psu.2018.27.

Fadhilla, A., Hafni, K. N., & Simamora, A.H., (2015), “Pengaruh Limbah Abu Pembakaran Biomassa Kelapa Sawit Terhadap Sifat-Sifat Fisika Dan Mekanik High Impact Polystyrene”, Jurnal Teknik Kimia USU, Vol 4(3), 23–28. https://doi.org/10.32734/jtk.v4i3.1477.

Houston, & Yahya D.F., (2012), “Rice Chemistry and Technology”, American Association on of Cereal Chemist.

Azizi, S. N., & Yousefpour, M. (2010), “Synthesis of Zeolite NaA and Analcime using Rice Husk as Silica Source without using Organic Template”, Journal of Materials Science, 45: 5692-5.

Ningsih, T., Chairunnisa, R., & Miskah, S. (2012), “Pemanfaatan Abu Kerak Boiler Hasil Pembakaran Limbah Kelapa Sawit sebagai Pengganti Parsila Pasir pada Pembuatan Beton”, Positron, 5(1): 26-29. https://doi.org/10.26418/positron.v5il.9744.

Prianti, E., Malino, M. B., & Lapanporo, B. P., (2015), “Pemanfaatan Abu Kerak Boiler Hasil Pembakaran Limbah Kelapa Sawit Sebagai Pengganti Parsial Pasir pada Pembuatan Beton”, Positron, Vol 5(1), 26–29. https://doi.org/10.26418/positron.v5i1.9744.

Putranto V.H, E. Kusumastuti, & Jumaeri, (2015), “Pemanfaatan Zeolit dari Abu Sekam Padi dengan Aktivasi Asam untuk Penurunan Kesadahan Air, Indonesian Journal of Mathematics and Natural Sciences ,Vol 32(2):164-174.

Ahmad, Mohd, Rafatullah, Arniza Ghazali, Othman Sulaiman, & Rokiah Hashim, (2011), “Oil Palm Biomass–Based Adsorbents for The Removal of Water Pollutants-A Review”, Journal of Environmental Science and Health, Part C, Vol 29(3): 177-222.

Oktavianty, H., Sunardi, S., & Wardani, R. M. A. A. S., (2021), “Sintesis Zeolit dari Ekstrak Sekam Padi Dan Kaleng Bekas Sebagai Adsorben Penurunan Kesadahan Air”, Jurnal Ilmiah Rekayasa Pertanian Dan Biosistem, Vol 9(2), 185–192. https://doi.org/10.29303/jrpb.v9i2.293.

Lumaela, A. K., Otok, B. W., & Ssutikno. (2013), “Pemodelan Chemical Oxygen Demand (COD) Sungai di Surabaya dengan Metode Mixed Geographically Weighted Regression”, Jurnal Sains & Seni”, 2(1): D100-105. https://doi.org/10.12962/j23373520.v2i1.3204.

Dewi, Y. S., & Buchori, Y. (2016). “Penurunan COD, TSS pada Penyaringan Air Limbah Tahu Menggunakan Media Kombinasi Pasir Kuarsa, Karbon Aktif, Sekam Padi dan Zeolit”, Jurnal Universitas Satya Negara Indonesia, 9(1): 74-80.

Novianti, D. L., & Tuhu, A. (2014), “Penurunan TSS dan Warna Llimbah Industri Batik secara Elektro Koagulasi”, Envirotek: Jurnal Ilmiah Teknik Lingkungan, 6(1): 37-44.

Oktavianty, H., (2022), “Sintesis Zeolit X dari Fly Ash Boiler Pabrik Kelapa Sawit sebagai Adsorben Pemurnian Biodiesel”, Sang Pencerah, Vol 8(2): 430-443. https://doi.org/10.35326/pencerah.v8i2.1938.

Oktavianty, H., Sunardi, S., & Wardani, R. M. A. A. S., (2021), “Sintesis Zeolit dari Ekstrak Sekam Padi Dan Kaleng Bekas Sebagai Adsorben Penurunan Kesadahan Air”, Jurnal Ilmiah Rekayasa Pertanian Dan Biosistem, Vol 9(2), 185–192. https://doi.org/10.29303/jrpb.v9i2.293.

Downloads

Published

2023-03-10