Rubber Industry Wastewater Treatment Using A Combination Of Ozonation And Modified PES-Nano ZnO Membranes
DOI:
https://doi.org/10.26555/chemica.v9i3.24658Keywords:
Ozonation, Wastewater, Membrane, Polyethersulfone (PES), Rubber IndustryAbstract
Until now, the application of a combination of biological, physical, and chemical methods to eliminate contaminants from the rubber industry wastewater has not been reported. The purpose of our investigation is to analyze the use of membrane techniques and the effect of pre-treatment of industrial rubber wastewater—pre-treatment by ozone on the performance of the modified PES-nano ZnO membrane. Modified PES-nano ZnO membranes were made with phase inversion techniques and membrane performance based on flux and rejection. Filtration processes with cross-flow filtration systems and ozonation time variations were 1, 2, 3 hours. The ozonation process influenced membrane rejection. The membrane rejection value increased to 89.6%, and ammonia decreased to 4.3 mg/L. The flux value increased to 10.2 L.M-2.h-1 in 1h Ozonatian and decreased with the increasing of filtration time. Pre-treatment with ozonation can increase membrane selectivity and extend membrane life during the filtration process due to reduced fouling. The pre-treatment process time with 3 hours-ozonation was the most violent rejection even though the flux value has decreasedReferences
T. E. Agustina, E. J. Sirait, and H. Silalahi, “Treatment of rubber industry wastewater by using fenton reagent and activated carbon,” J. Teknol., vol. 79, no. 7–2, pp. 31–37, 2017, doi: 10.11113/jt.v79.11872.
N. A. M. Nazri, W. J. Lau, A. F. Ismail, T. Matsuura, D. Veerasamy, and N. Hilal, “Performance of PAN-based membranes with graft copolymers bearing hydrophilic PVA and PAN segments in direct ultrafiltration of natural rubber effluent,” Desalination, vol. 358, pp. 49–60, 2015, doi: 10.1016/j.desal.2014.12.012.
H. P. J. S. Pillai and K. Girish, “Rubber processing industry effluent treatment using a bacterial consortium,” Int. J. Curr. Microbiol. Appl. Sci., vol. 3, no. 10, pp. 775–782, 2014.
M. Mohammadi, H. C. Man, M. A. Hassan, and P. L. Yee, “Treatment of wastewater from rubber industry in Malaysia,” African J. Biotechnol., vol. 9, no. 38, pp. 6233–6243, 2010, doi: 10.5897/AJB09.031.
M. Massoudinejad, “Treatment of natural rubber industry wastewater through a combination of physicochemical and ozonation processes,” J. Adv. Environ. Heal. Res., vol. 3, no. 4, 2015, doi: 10.22103/jaehr.2015.40208.
H. N. Nguyen and T. T. Luong, “Situation of wastewater treatment of natural rubber latex processing in the Southeastern region, Vietnam,” J. Vietnamese Environ., vol. 2, no. 2, pp. 58–64, 2012, doi: 10.13141/jve.vol2.no2.pp58-64.
N. M. N. Sulaiman, S. Ibrahim, and S. L. Abdullah, “Membrane Bioreactor for the treatment of natural rubber wastewater,” Int. J. Environ. Eng., 2010, doi: 10.1504/ijee.2010.029823.
C. P. Leo, W. P. Cathie Lee, A. L. Ahmad, and A. W. Mohammad, “Polysulfone membranes blended with ZnO nanoparticles for reducing fouling by oleic acid,” Sep. Purif. Technol., vol. 89, pp. 51–56, 2012, doi: 10.1016/j.seppur.2012.01.002.
H. Hyung, S. Lee, J. Yoon, and C. H. Lee, “Effect of preozonation on flux and water quality in ozonation-ultrafiltration hybrid system for water treatment,” Ozone Sci. Eng., vol. 22, no. 6, pp. 637–652, 2000, doi: 10.1080/01919510009408804.
G. Veréb et al., “Effects of pre-ozonation in case of microfiltration of oil contaminated waters using polyethersulfone membrane at various filtration conditions,” Desalin. Water Treat., vol. 73, no. May 2016, pp. 409–414, 2017, doi: 10.5004/dwt.2017.20518.
L. Shen et al., “Preparation and characterization of ZnO/polyethersulfone (PES) hybrid membranes,” Desalination, vol. 293, no. 2012, pp. 21–29, 2012, doi: 10.1016/j.desal.2012.02.019.
T. D. Kusworo, N. Aryanti, R. A. Anggita, T. A. D. Setyorini, and D. P. Utomo, “Surface modification and performance enhancement of polyethersulfone (PES) membrane using combination of ultra violet irradiation and thermal annealing for produced water treatment,” J. Environ. Sci. Technol., vol. 10, no. 1, pp. 35–43, 2017, doi: 10.3923/jest.2017.35.43.
C. P. Leo, W. P. Cathie Lee, A. L. Ahmad, and A. W. Mohammad, “Polysulfone membranes blended with ZnO nanoparticles for reducing fouling by oleic acid,” Sep. Purif. Technol., vol. 89, pp. 51–56, 2012, doi: 10.1016/j.seppur.2012.01.002.
W. Gao et al., “Membrane fouling control in ultrafiltration technology for drinking water production: A review,” Desalination. 2011. doi: 10.1016/j.desal.2011.01.051.
L. Li, J. Hou, Y. Ye, J. Mansouri, and V. Chen, “Composite PVA/PVDF pervaporation membrane for concentrated brine desalination: Salt rejection, membrane fouling and defect control,” Desalination, vol. 422, no. August, pp. 49–58, 2017, doi: 10.1016/j.desal.2017.08.011.
T. D. Kusworo et al., “Evaluation of Integrated modified nanohybrid polyethersulfone-ZnO membrane with single stage and double stage system for produced water treatment into clean water,” J. Water Process Eng., vol. 23, no. January, pp. 239–249, 2018, doi: 10.1016/j.jwpe.2018.04.002.
G. L. Zhuang, M. Y. Wey, and H. H. Tseng, “The density and crystallinity properties of PPO-silica mixed-matrix membranes produced via the in situ sol-gel method for H2/CO2 separation. II: Effect of thermal annealing treatment,” Chem. Eng. Res. Des., vol. 104, pp. 319–332, 2015, doi: 10.1016/j.cherd.2015.08.020.
D. Koo, A. Du, G. R. Palmese, and R. A. Cairncross, “Moisture management of polylactides: The effect of heat treatment,” Polymer (Guildf)., 2012, doi: 10.1016/j.polymer.2012.01.024.
V. K. Gupta, B. Gupta, A. Rastogi, S. Agarwal, and A. Nayak, “Pesticides removal from waste water by activated carbon prepared from waste rubber tire,” Water Res., vol. 45, no. 13, pp. 4047–4055, 2011, doi: 10.1016/j.watres.2011.05.016.
S. H. You, D. H. Tseng, and W. C. Hsu, “Effect and mechanism of ultrafiltration membrane fouling removal by ozonation,” Desalination, vol. 202, no. 1–3, pp. 224–230, 2007, doi: 10.1016/j.desal.2005.12.058.
Y. Hu et al., “Combined tio2 membrane filtration and ozonation for efficient water treatment to enhance the reuse of wastewater,” Desalin. Water Treat., vol. 34, no. 1–3, pp. 57–62, 2011, doi: 10.5004/dwt.2011.2867.
Z. L. Kiss, L. Kocsis, G. Keszthelyi-Szabó, C. Hodúr, and Z. László, “Treatment of oily wastewater by combining ozonation and microfiltration,” Desalin. Water Treat., vol. 55, no. 13, pp. 3662–3669, 2015, doi: 10.1080/19443994.2014.939877.
N. Aryanti, T. D. Kusworo, W. Oktiawan, and D. H. Wardhani, “Performance of ultrafiltration-ozone combined system for produced water treatment,” Period. Polytech. Chem. Eng., vol. 63, no. 3, pp. 438–447, 2019, doi: 10.3311/PPch.13491.
Q. Zhang, C. Zhang, J. Xu, Y. Nie, S. Li, and S. Zhang, “Effect of poly(vinyl alcohol) coating process conditions on the properties and performance of polyamide reverse osmosis membranes,” Desalination, vol. 379, pp. 42–52, 2016, doi: 10.1016/j.desal.2015.10.012.
A. B. C. Alvares, C. Diaper, and S. A. Parsons, “Partial oxidation by ozone to remove recalcitrance from wastewaters - a review,” Environ. Technol. (United Kingdom), vol. 22, no. 4, pp. 409–427, 2001, doi: 10.1080/09593332208618273
Downloads
Published
Issue
Section
License
Chemica: Jurnal Teknik Kimia allows readers to read, download, copy, distribute, print, search, or link to its articles' full texts and allows readers to use them for any other lawful purpose. The journal allows the author(s) to hold the copyright without restrictions. Finally, the journal allows the author(s) to retain publishing rights without restrictions
- Authors are allowed to archive their submitted articles in an open access repository
- Authors are allowed to archive the final published article in an open access repository with an acknowledgment of its initial publication in this journal
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 Generic License.
Â