Pyrolysis of Spirulina platensis Residue: Effect of Temperature without and with Fe-oxide catalyst
DOI:
https://doi.org/10.26555/chemica.v7i2.18077Keywords:
Bio-oil, Fe-oxide, Pyrolysis, Spirulina platensis residueAbstract
The limited reserves of fuel must resolve immediately. One of the renewable energy solutions that have the potential to come from biomass sources is microalgae. The advantages of microalgae compared to other biomass is the oil produced, the speed of growth, and it does not interfere with food availability. The processing of residual Spirulina platensis microalgae (SPR) by pyrolysis is exciting to do, does not cause pollution, and the technology is simple. This study's purpose was SPR pyrolysis with a grain size of 140 mesh without and with five (5) wt.% Fe-oxide catalyst. The variables studied were temperature on the yield of bio-oil products, water phase, charcoal, and gas. Pyrolysis was carried out in a fixed bed reactor at 300, 400, 500, 550, and 600 â°C. The higher the pyrolysis temperature, the higher the bio-oil yield, with the optimum catalyst at 400 â°C produced 15.34% and without a catalyst at a temperature of 500 â°C, namely 15.00%. The water yield phase in the range of 300-600 â°C is higher for catalyst use (30-39 %) than without catalyst (13.75-22.25%). The higher the pyrolysis temperature, the lower the yield char. The yield of gas without a catalyst was higher in the range of 30.69-38.94% compared to catalyst 12.58-26.18%. At a temperature of 300 â°C without a catalyst, the conversion obtained was 48.69%, while with a catalyst, 60.08%References
Badan pengkajian dan Penerapan Teknologi−Outlook Energi Indonesia 2019. (BPPT−OEI, 2019).
S. Jamilatun, Budhijanto, Rochmadi, and A. Budiman, “Thermal Decomposition and Kinetic Studies of Pyrolysis of Secondary cracking. International Journal of Renewable Energy Development, 6(3), 193–201, 2017.
S. Jamilatun, D. Kusuma, ASS. Shakti dan F. Ferdiant, "Pembuatan Biocoal Sebagai Bahan Bakar Alternatif dari Batubara dengan Campuran Arang Serbuk Gergaji Kayu Jati, Glugu dan Sekam Padi", Prosiding Seminar Nasional Teknik Kimia “Kejuanganâ€, Pengembangan Teknologi Kimia untuk PengolahanSumber Daya Alam Indonesia, ISSN 1693 – 4393, 2010.
C. Kilic, Gokhan, SAkl. and Gokpinar, S., “Comparing to The Vomit of In Two Different Spirulina platensis Growth Featuresâ€, Fish Aquat. Sci., 23, 189-192. 2006.
S. Jamilatun, Budhijanto, Rochmadi, A. Yuliestyan, H. Hadiyanto, and A. Budiman, “Comparative analysis between pyrolysis products of Spirulina platensis biomass and its residuesâ€, Int. J. Renew. Energy Dev., vol. 8, no. 2, pp. 133–140, 2019.
A. Campanella, R. Muncrief, M.P. Harold, D.C. Griffith, N.M. Whitton, and R.S. Weber, “Thermolysis of microalgae and duckweed in a CO2- wept fixed-bed reactor: Bio-oil yield and compositional effectsâ€. Bioresource Technology, 109, 154-162, 2012.
S.O. Gultom, C. Zamalloa, and B. Hu, “Microalgae Harvest through Fungal PalletizationCo-Culture of Chlorella Vulgaris and Aspergillus nigerâ€. Journal Energies. 7(7):4417-442, 2014.
S. Jamilatun, Budhijanto, Rochmadi, A. Yuliestyan, and A. Budiman, “Valuable Chemicals Derived from Pyrolysis Liquid Products of Secondary crackingâ€, Indones. J. Chem., 19 (3), 703 – 711, 2019.
Z. Du, “Thermochemical Conversion of Microalgae for Biofuel Productionâ€, Disertasi. University of Minnesota: Minnesota, 2013.
X. Miao, Q. Wu, and C. Yang, “Fast pyrolysis of microalgae to produce renewable Fuelsâ€, J. Anal. Appl. Pyrol., 71, 855–863, 2004.
S. Jamilatun, Budhijanto, Rochmadi, A. Yuliestyan, and A. Budiman, “Effect of grain size, temperature and catalyst amount on pyrolysis products of Spirulina Platensis Residue (SPR)â€, International Journal of Technology 10(3), 541-550, 2019
L. Chen, and K. Yoshikawa, “Bio-oil upgrading by cracking in two-stage heated reactorsâ€. AIMS Energy, 6(1): 203–215, 2018.
D. Houshmand, B. Roozbehani, and A. Badakhshan, “Thermal and Catalytic Degradation of Polystyrene with a Novel Catalystâ€. Journal Emerging Technologies, 5(1), 234 -238, 2016.
S. Jamilatun, A. Budiman, H. Anggorowati, A. Yuliestyan, Y. Surya Pradana, Budhijanto, and Rochmadi, “Ex-Situ Catalytic Upgrading of Secondary cracking oil using silica-alumina catalystâ€, Int. J. Renew. Energy Res. Vol. 9, No. 4, pp. 1733−1740.
U. Jena, and K.C. Das, “Comparative Evaluation of Thermochemical
Liquefaction and Pyrolysis for Bio-Oil Production from Microalgaeâ€, Energy & Fuels, 25, 5472-5482, 2011.
A. Baimoldina, K. Papadakis, and E.Y. Konysheva, “Diverse impact of α-Fe2O3 with nano/micro-sized shapes on the catalytic fast pyrolysis of pinewood: Py-GC/MS studyâ€, Analytical and Applied Pyrolysis, 139, 145–155, 2019.
S. Jamilatun dan S. Salamah, "Pemanfaatan Asap Cair Food Grade yang Dimurnikan dengan Arang Aktif sebagai Pengawet Ikan Nila", Eksergi, 14 (2), 29-34, 2017.
P.S. Rezaei, H. Shafaghat, W. Daud, “Production of green aromatic and olefins by catalytic cracking oxygenated compounds derived from biomass pyrolysisâ€, Appl.Catal. A: Gen., 490(5) 11, 2011.
P. Pan, C.W. Hu, W.Y. Yang, Y.S. Li, L.L. Dong, L.F. Zhu, D.M. Tong, R.W. Qing, and Y. Fan, “The direct pyrolysis and catalytic pyrolysis of Nannochloropsis sp residue for renewable bio-oilsâ€, Bioresource Technology, 101, 4593-4599, 2011.
T. Dickerson, and J. Soria, “Catalytic fast pyrolysis: A Reviewâ€, Energy, 6, 514-538, 2013.
Y. Yuan, T. Wang, and Q. Li, “Production of lowcarbon light olefins from catalytic cracking of crude bio-oilâ€, Chin. J. Chem. Phys., 26920, 237 – 244, 2013.
D.R. Vardon, B.K. Sharma, G.V. Blazina, K. Rajagopalan, T.J. Strathmann, “Thermochemical conversion of raw and defatted algal biomass via hydrothermal liquefaction and slow pyrolysisâ€, Bioresource Technology, 109, 178-87, 2012.
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