Comparison of Hexane, Methanol, and Their Mixtures as Solvents for Microalgae Lipid Extraction by Hydrodynamic Cavitation

Authors

  • Martomo Setyawan (SCOPUS ID: 57003357800) Universitas Ahmad Dahlan
  • Siti Jamilatun Universitas Ahmad Dahlan
  • Muhammad Nufail Syafii Universitas Ahmad Dahlan
  • Resyaldi Pratama Universitas Ahmad Dahlan

DOI:

https://doi.org/10.26555/chemica.v7i2.16803

Keywords:

Biodiesel, Extraction, Hydrodynamic Cavitation, Microalgae Lipids, Solvent combination

Abstract

The process of producing biodiesel from microalgae as an effort to solve energy problems is currently constrained by the negative energy balance, which requires more energy to produce than the heating value of biodiesel. The lipid extraction assisted by hydrodynamic cavitation requires less energy extraction than the heating value of biodiesel. The effort to increase the energy efficiency of the hydrodynamic cavitation extraction process is to find a solvent that has a low boiling point. This study aims to improve energy efficiency by using a solvent mixture of hexane and methanol, which has a low boiling point. The results showed that the methanol hexane mixture with a volume ratio of 4:1 gave the lowest mixture boiling point of 51.2 °C with a yield of 3.28% g lipid/ g dry microalgae. The process runs at a temperature of 30 °C with a driving pressure of 5 kg/cm2, with an extraction energy requirement of 2 kJ/g of lipids. This process is feasible to be developed to produce biodiesel from microalgae with a positive energy balance.

Author Biographies

Martomo Setyawan, (SCOPUS ID: 57003357800) Universitas Ahmad Dahlan

Department of Chemical Engineering

Siti Jamilatun, Universitas Ahmad Dahlan

Department of Chemical Engineering

Muhammad Nufail Syafii, Universitas Ahmad Dahlan

Department of Chemical Engineering

Resyaldi Pratama, Universitas Ahmad Dahlan

Department of Chemical Engineering

References

Y. S. Pradana, H. Sudibyo, E. A. Suyono, Indarto, and A. Budiman, “Oil algae extraction of selected microalgae species grown in monoculture and mixed cultures for biodiesel production,†Energy Procedia, vol. 105, pp. 277–282, 2017.

T. M. Mata, A. A. Martins, and N. S. Caetano, “Microalgae for biodiesel production and other applications: A review,†Renew. Sustain. Energy Rev., vol. 14, no. 1, pp. 217–232, 2010.

J. P. Maity, J. Bundschuh, C. Y. Chen, and P. Bhattacharya, “Microalgae for third generation biofuel production, mitigation ofgreenhouse gas emissions and wastewater treatment: Present and future perspectives - A mini review,†Energy, vol. 78, pp. 104–113, 2014.

T. Suganya, M. Varman, H. H. Masjuki, and S. Renganathan, “Macroalgae and microalgae as a potential source for commercial applications along with biofuels production: A biorefinery approach,†Renew. Sustain. Energy Rev., vol. 55, pp. 909–941, 2016.

Sunarno, Rochmadi, P. Mulyono, M. Aziz, and A. Budiman, “Kinetic study of catalytic cracking of bio-oil over silica-alumina catalyst,†BioResources, vol. 13, no. 1, pp. 1917–1929, 2018.

D. R. Sawitri, Sutijan, and A. Budiman, “Kinetics study of free fatty acids esterification for biodiesel production from palm fatty acid distillate catalysed by sulphated zirconia,†ARPN J. Eng. Appl. Sci., vol. 11, no. 16, pp. 9951–9957, 2016.

Daniyanto, Sutijan, Deendarlianto, and A. Budiman, “Reaction kinetic of pyrolysis in mechanism of pyrolysis gasification process of dry torrified sugarcane bagasse,†ARPN J. Eng. Appl. Sci., vol. 11, no. 16, pp. 9974–9980, 2016.

D. R. Wicakso, M. Hidayat, and R. B. Cahyono, “Effect of temperature on catalytic decomposition of tar using Indonesian iron ore as catalyst,†Int. J. Renew. Energy Res., vol. 8, no. 1, 2018.

S. Jamilatun, A. Budiman, Budhijanto, and Rochmadi, “Non-catalytic slow pyrolysis of Spirulina Platensis residue for production of liquid biofuel,†Int. J. Renew. ENERGY Res. S. Jamilatun al, vol. 7, no. 4, 2017.

R. D. Kusumaningtyas, I. N. Aji, H. Hadiyanto, and A. Budiman, “Application of tin (II) chloride catalyst for high FFA Jatropha oil esterification in continuous reactive distillation column,†Bull. Chem. React. Eng. Catal., vol. 11, no. 1, p. 66, 2016.

M. Maisarah, C. P. C. Bong, W. Shin, and J. Shiun, “Review on the Suitability of Waste for Appropriate Waste-to- Energy Technology,†vol. 63, pp. 187–192, 2018.

H. Kamyab, S. Chelliapan, and M. Fadhil, “Isolate New Microalgal Strain for Biodiesel Production and Using FTIR Spectroscopy for Assessment of Pollutant Removal from Palm Oil Mill Effluent ( POME ),†vol. 63, pp. 91–96, 2018.

N. Nabila, A. Hamid, and J. S. Lim, “Techno-economic Assessment of an Integrated Algae-based Biorefinery with Palm Oil Mill,†vol. 63, no. 2014, pp. 169–174, 2018.

E. Suali and R. Sarbatly, “Conversion of microalgae to biofuel,†Renew. Sustain. Energy Rev., vol. 16, no. 6, pp. 4316–4342, 2012.

A. K. Lee, D. M. Lewis, and P. J. Ashman, “Microalgal cell disruption by hydrodynamic cavitation for the production of biofuels,†J. Appl. Phycol., vol. 27, no. 5, pp. 1881–1889, 2015.

M. Setyawan, A. Budİman, P. Mulyono, and Sutijan, “Optimum extraction of algae-oil from microalgae using hydrodynamic cavitation,†Int. J. Renew. Energy Res., vol. 8, no. 1, 2018.

A. K. Lee, D. M. Lewis, and P. J. Ashman, “Disruption of microalgal cells for the extraction of lipids for biofuels: Processes and specific energy requirements,†Biomass and Bioenergy, vol. 46, pp. 89–101, 2012.

I. Lee and J. I. Han, “Simultaneous treatment (cell disruption and lipid extraction) of wet microalgae using hydrodynamic cavitation for enhancing the lipid yield,†Bioresour. Technol., vol. 186, pp. 246–251, 2015.

J.-P. Franc and J.-M. Michel, Fundamentals of Cavitation. New York: Kluwer Academic Publishers, 2005.

G. Knothe and K. R. Steidley, “Kinematic viscosity of biodiesel fuel components and related compounds. Influence of compound structure and comparison to petrodiesel fuel components,†Fuel, vol. 84, no. 9, pp. 1059–1065, 2005.

B. E. Poling, G. H. Thomson, D. G. Friend, R. L. Rowley, and W. V. Wilding, “Section 2: Physical and Chemical Data,†in Perry’s Chemical Engineers’ Handbook, 2007, pp. 1–517.

F. Yang, W. Xiang, X. Sun, H. Wu, T. Li, and L. Long, “A novel lipid extraction method from wet microalga Picochlorum sp. at room temperature,†Mar. Drugs, vol. 12, no. 3, pp. 1258–1270, 2014.

R. Halim, M. K. Danquah, and P. A. Webley, “Extraction of oil from microalgae for biodiesel production: A review,†Biotechnol. Adv., vol. 30, no. 3, pp. 709–732, 2012.

N. Grimi, A. Dubois, L. Marchal, S. Jubeau, N. I. Lebovka, and E. Vorobiev, “Selective extraction from microalgae Nannochloropsis sp. using different methods of cell disruption,†Bioresour. Technol., vol. 153, pp. 254–259, 2014.

M. Setyawan, P. Mulyono, Sutijan, and A. Budiman, “Comparison of Nannochloropsis sp . cells disruption between hydrodynamic cavitation and conventional extraction,†in MATEC Web of Conferences, 2018, vol. 01023, pp. 1–5.

E. G. Giakoumis and C. K. Sarakatsanis, “Estimation of biodiesel cetane number, density, kinematic viscosity and heating values from its fatty acid weight composition,†Fuel, vol. 222, no. March, pp. 574–585, 2018.

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Published

2021-01-19