The Effect of Single and Double Activation with Potassium Hydroxide 2N on Charcoal from Fir Wood (Casuarina Junghuhniana) Pyrolysis
DOI:
https://doi.org/10.26555/chemica.v7i1.15651Keywords:
KOH Activation, Carbon Active, Pyrolysis, Pine WoodAbstract
The purpose of this study was to know the influence of the single and double activation by using calcium hydroxide (KOH) with a concentration of 2N. The activation of KOH 2N applied in the activated carbon from pine wood. The activated carbon made through the pyrolysis process with a temperature variation of 500-600 ℃ for about 180 minutes. The experiment performed in two ways: (i) single activation of KOH 2N and (ii) double activation of KOH 2N. The effects of ash content and Iod absorption content in activated carbon were studied. The results showed that the ash content about 8-30% and Iod absorption content about 317.25-507.60 mg Iod/gram carbon. The results of this study standardized by using the Indonesia National Standards (SNI) method. The result also indicated that the single activation was better than double activation of KOH.References
I. Suyata, "Optimasi penurunan nilai BOD, COD, dan TSS limbah cair industri tapioka menggunakan arang aktif dari ampas kopi", J. Mol., vol. 5, no. 5, pp. 22–23, 2010.
S. Jamilatun dan Salamah, S., "Peningkatan Kualitas Asap Cair dengan Menggunakan Arang Aktif", SNTT FGDT 2015, Universitas Muhammadiyah Surakarta.
K. Riyani, "Pengaruh karbon aktif terhadap aktivitas foto degradasi zat warna pada limbah cair industri tekstil menggunakan fotokatalis TiO2", J. Mol., vol. 6, no. 2, pp. 113–122.
S. Jamilatun, Intan Dwi, I., Elza Novita, P, "Karakteristik Arang Aktif dari Tempurung Kelapa dengan Pengaktivasi H2SO4 Variasi Suhu dan Waktu", Simposium Nasional Teknologi Terapan (SNTT) II 2014, Universitas Muhammadiyah Surakarta, ISSN: 2339-028X, 2015.
C. Nieto-Delgado, J. Gutiérrez-MartÃnez, and J. R. Rangel-Méndez, “Modified activated carbon with interconnected fibrils of iron-oxyhydroxides using Mn 2 + as morphology regulator, for a superior arsenic removal from water,†J. Environ. Sci. (China), vol. 76, pp. 403–414, 2018, doi: 10.1016/j.jes.2018.06.002.
Y. S. Jeong, “Lab-scale and pilot-scale two-stage gasification of biomass using active carbon for production of hydrogen-rich and low-tar producer gas,†Fuel Process. Technol., vol. 198, no. October 2019, p. 106240, 2020, doi: 10.1016/j.fuproc.2019.106240.
T. A. Buscheck et al., “Integrated geothermal CO2 reservoir systems: Reducing carbon intensity through sustainable energy production and secure CO2 storage,†Energy Procedia, vol. 37, pp. 6587–6594, 2013, doi: 10.1016/j.egypro.2013.06.591.
S. Jamilatun, Aslihati, L. dan Suminar, E.W, "Pengaruh perendaman ikan nila dengan asap cair (liquid smoke) terhadap daya simpan", Prosiding Semnastek, 2016.
P. Patandung, “Pengaruh jenis aktivator terhadap kualitas arang aktif dari tempurung kemiri ( aleuritis moluccana willd ) the effect of activator on the quality of activated charcoal for candlenut,†J. Penelit. Teknol. Ind., vol. 9, no. 2, pp. 107–114, 2017.
G. Ravenni, O. H. Elhami, J. Ahrenfeldt, U. B. Henriksen, and Y. Neubauer, “Adsorption and decomposition of tar model compounds over the surface of gasification char and active carbon within the temperature range 250–800 °C,†Appl. Energy, vol. 241, no. March, pp. 139–151, 2019, doi: 10.1016/j.apenergy.2019.03.032.
KB. Oyo, Igbokwe PK, "Production of activated carbon from coconut-shell". J. Chem.Soc. Nig., 26(1): 91-94, 2001.
A. Putra, 2019 “Preparation and Characterization of Activated Carbon from Waste of Jengkol Shell ( Pithecellobium jiringa ),†Int. J. Progress. Sci. Technol., vol. 15, no. 2, pp. 320–327.
S. Jamilatun dan S. Salamah, "Pemanfaatan Asap Cair Food Grade yang Dimurnikan dengan Arang Aktif sebagai Pengawet Ikan Nila", Eksergi, 14 (2), 29-34, 2017.
Y. Aprianis, 2012, “Karakteristik Arang Aktif dari Tungga Accacia crassicarpa,†J. Penelit. Has. Hutan, vol. 30, no. 4, pp. 261–268, 2012.
F. Dwi Kurniati S. Podoyo, “Sintesis Arang Aktif dari Tempurung Kelapa dan Aplikasinya Untuk Adsorpsi Asap Cair,†J. Kim. Sains dan Apl., vol. 14, no. 3, pp. 72–76, 2011.
G. Pambayun, R. Y. E. Yulianto., M. Rachimoellah, E., M. M. Putri, “Pembuatan karbon aktif dari arang tempurung kelapa dengan aktivator ZnCL2 dan sebagai adsorben untuk mengurangi kadar fenol dalam air limbah,†J. Tek. Pomits, vol. 2, no. 1, 2013.
S. Jayanti dan Sumarni, N., “Kajian Arang Aktif Biji Asam Jawa (Tamarindus Indica Linn) Menggunakan Aktivator H3PO4 Pada Penyerapan Logam Timbal,†J. Ris. Kim., vol. 1, no. 1, pp. 13–19, 2015.
A. V. Bridgwater, “Renewable fuels and chemicals by thermal processing of biomass,†Chem. Eng. J., vol. 91, no. 2–3, pp. 87–102, 2003, doi: 10.1016/S1385-8947(02)00142-0.
T. Bhaskar, B. Bhavya, R. Singh, D. V. Naik, A. Kumar, and H. B. Goyal, “Thermochemical conversion of biomass to biofuels,†Biofuels, pp. 51–77, 2011, doi: 10.1016/B978-0-12-385099-7.00003-6.
I. Mufandi, W. Treedet, P. Singbua, and R. Suntivarakorn, “Produksi bio-oil dari rumput gajah dengan fast pyrolysis menggunakan circulating fluidized bed reactor (CFBr) dengan kapasitas 45 kg/h,†Chem. J. Tek. Kim., vol. 5, no. 2, p. 37, 2019, doi: 10.26555/chemica.v5i2.12484.
I. Mufandi, Treede, P. Singbua, and R. Suntivarakorn, “The Comparison of Bio-oil Production from Sugarcane Trash , Napier Grass , and Rubber Tree in The Circulating Fluidized Bed Reactor,†TEST Eng. Manag. J., vol. 82, no. 4557, pp. 4557–4563, 2020.
W. Treedet and R. Suntivarakorn, “Design and operation of a low cost bio-oil fast pyrolysis from sugarcane bagasse on circulating fluidized bed reactor in a pilot plant,†Fuel Process. Technol., vol. 179, no. March, pp. 17–31, Oct. 2018, doi: 10.1016/j.fuproc.2018.06.006.
W. Treedet and R. Suntivarakorn, “Sugar Cane Trash Pyrolysis for Bio-oil Production in a Fluidized Bed Reactor,†pp. 140–147, 2011, doi: 10.3384/ecp11057140.
J. L. Zheng, “Pyrolysis oil from fast pyrolysis of maize stalk,†J. Anal. Appl. Pyrolysis, vol. 83, no. 2, pp. 205–212, 2008, doi: 10.1016/j.jaap.2008.08.005.
A. Pattiya, “Bio-oil production via fast pyrolysis of biomass residues from cassava plants in a fluidised-bed reactor,†Bioresour. Technol., vol. 102, no. 2, pp. 1959–1967, 2011, doi: 10.1016/j.biortech.2010.08.117.
S. Jamilatun, M. Setyawan, S. Salamah, D.A., Ayu Purnama, R. Melani Putri,"Pembuatan Arang Aktif Dari Tempurung Kelapa Dengan Aktivasi Sebelum dan Susudah Pirolisis", Seminar Nasional Sains dan Teknologi 2015, Universitas Muhammadiyah Jakarta, 2407-1846 (Print) 2460-8416 (Online), 2015.
Standar Nasional Indonesia, 2015 (SNI) 06-3730-2015:" Arang Aktif Teknis". Jakarta: Dewan Standarisasi Nasional.
L. M. Yuningsih, D. Mulyadi, and A. J. Kurnia, “Pengaruh Aktivasi Arang Aktif dari Tongkol Jagung dan Tempurung Kelapa Terhadap Luas Permukaan dan Daya Jerap Iodin,†J. Kim. Val., vol. 2, no. 1, pp. 30–34, 2016.
M. Paputungan dan H. Iyabu, “Pengaruh Aktivator HCl dan H3PO4 terhadap Karakteristik ( Morfologi Pori ) Arang Aktif Tempurung Kelapa serta Uji Adsorpsi pada Logam Timbal ( Pb ),†J. Entropi, vol. 13, no. 1, pp. 67–75, 2018.
S. Jamilatun, D. Kusuma, ASS. Shakti dan F. Ferdiant, "Pembuatan Biocoal Sebagai Bahan Bakar Alternatif dari Batubara dengan Campuran Arang Serbuk Gergaji Kayu Jati, Glugu dan Sekam Padi", Prosiding Seminar Nasional Teknik Kimia “Kejuangan†, Pengembangan Teknologi Kimia untuk PengolahanSumber Daya Alam Indonesia , ISSN 1693 – 4393, 2010.
Downloads
Published
Issue
Section
License
Chemica: Jurnal Teknik Kimia allows readers to read, download, copy, distribute, print, search, or link to its articles' full texts and allows readers to use them for any other lawful purpose. The journal allows the author(s) to hold the copyright without restrictions. Finally, the journal allows the author(s) to retain publishing rights without restrictions
- Authors are allowed to archive their submitted articles in an open access repository
- Authors are allowed to archive the final published article in an open access repository with an acknowledgment of its initial publication in this journal
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 Generic License.
Â